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What is measuredpH, phosphate, potash & magnesiumThe "standard soil analysis package" measures soil acidity (pH) and estimates the plant-availableconcentrations of the major nutrients in the soil - phosphorus (P), potassium (K) and magnesium (Mg). Soil acidity is measured as pH (the concentration of H+ ions) the scale running from pH 1 (very acid), through pH 7 (neutral) to pH 14 (very alkaline). The normal soil range is pH 4.5-8.5. The total P and K content of a soil can be measured exactly but has little relevance to crop yield because only a relatively small proportion of the total P and K in soils is available to the plant (see diagram). Soil analysis in the laboratory therefore uses chemical extractants to provide an estimate of the nutrient which would be available under field conditions. The results provide the best practical guide for determining P, K and Mg in the readily plant-available pool shown in the diagram. The methods of soil analysis used in the UK have been developed over many years and have been correlated to crop response on a wide range of soils in numerous field experiments. Other measurements of nutrient content or ratios may be made on soils, but unless there is dependable correlation with yields, they are of limited practical value. Calcium (Ca) and sodium (Na) can also be measured, but these are rarely determined.
Trace elementsOf the elements required in small amounts by crops - the 'trace' elements or 'micronutrients' - some can be measured effectively in soil, namely boron (B), chloride (Cl), copper (Cu), molybdenum (Mo), cobalt (Co) and zinc (Zn). Other elements which are not effectively assessed by soil measurements and need to be measured in herbage or in the animal include manganese (Mn), iodine (I) and selenium (Se). Heavy metalsIn the UK there are statutory soil limits for 7 potentially toxic elements (PTEs) to ensure compliance with EU legislation when sewage sludge is to be applied. These are the 'heavy metals' cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), mercury (Hg), nickel (Ni) and zinc (Zn). The total (acid extractable) content of each of these in soil is analysed. The regulations also link the level of these elements to pH which affects their availability to plants. The limits for PTEs are defined in the Sludge (Use in Agriculture) Regulations 1989 and given in the Defra Soil Code. The Code advises the same limits be used to guide the application of other metal containing organic manures and wastes applied to land. Nitrogen and sulphurMeasuring the availability of soil nitrogen (N) and sulphur (S) can be useful but is more complex than for other nutrients; these are not covered in this leaflet.
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